Advanced Organic Chemistry: Part A: Structure and Mechanisms by Francis A. Carey

By Francis A. Carey

The two-part, 5th version of complicated natural Chemistry has been considerably revised and reorganized for larger readability. the cloth has been up to date to mirror advances within the box because the earlier version, specially in computational chemistry. half A covers basic structural issues and easy mechanistic varieties. it could possibly stand-alone; jointly, with half B: response and Synthesis, the 2 volumes offer a entire origin for the examine in natural chemistry. spouse web pages supply electronic versions for examine of constitution, response and selectivity for college kids and workout suggestions for instructors.

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Example text

1 The ideas about bond length, bond energy, polarity, and polarizability discussed in this section are very useful because of the relative constancy of these properties from molecule to molecule. Thus, data obtained from simple well-studied molecules can provide a good guide to the properties of substances whose structures are known but which have yet to be studied in detail. Organic chemists have usually discussed this transferability of properties in terms of valence bond theory. Thus, the properties are thought of as characteristic of the various types of atoms and bonds.

Soc. 100, 6595 (1978); M. J. S. Dewar and G. P. Ford, 1. Am. Chem. Soc. 101, 5558 (1979); W. J. Hehre, Acc. Chern. Res. 9, 399 (1976); M. J. S. Dewar, E. G. Zoebisch, E. F. Healy, and J. J. P. Stewart, 1. Am. Chem. Soc. 107,3902 (1985); J. N. Levine, Quantum Chemistry, Third Edition, Allyn and Bacon, Boston, 1983, pp. 507-512; W. Hehre, L. Radom, P. v. R. Schleyer, and J. A. Pople, Ab Initio Molecular Orbital Calculations, Wiley·Interscience, New York, 1986, Chapter 6. 3. 11. 4 a. Energy comparisons are from M.

J. S. Dewar and G. P. Ford, 1. Am. Chem. Soc. 101, 5558 (1979); W. J. Hehre, Acc. Chern. Res. 9, 399 (1976); M. J. S. Dewar, E. G. Zoebisch, E. F. Healy, and J. J. P. Stewart, 1. Am. Chem. Soc. 107,3902 (1985); J. N. Levine, Quantum Chemistry, Third Edition, Allyn and Bacon, Boston, 1983, pp. 507-512; W. Hehre, L. Radom, P. v. R. Schleyer, and J. A. Pople, Ab Initio Molecular Orbital Calculations, Wiley·Interscience, New York, 1986, Chapter 6. 3. 11. 4 a. Energy comparisons are from M. J. S. Dewar, E.

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