Advances In Chemical Propulsion, Science To Technology by Roy,G D Ed

By Roy,G D Ed

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1993. Strained hydrocarbons. Benzvalene and derivatives. 6th ONR Propulsion Meeting Proceedings. University of Colorado at Boulder. 1–6. 2. Moriarty, R. , and M. S. Rao. 1994. Energetic azide compounds. 7th ONR Propulsion Meeting Proceedings. Eds. G. D. Roy and P. Givi. Buffalo, NY: State University of New York at Buffalo. 75–81. 3. Moriarty, R. , L. A. Enache, D. Pavlovic, and M. S. Rao. 1995. Synthesis of highenergy compounds. 8th ONR Propulsion Meeting Proceedings. Eds. G. D. Roy and F. A. Williams.

1). This is partly due to the strain energy in the molecules. Research Accomplishments In the pursuit of new high-energy-density fuels, fuels with strained molecules have been developed and their combustion characteristics studied [1]. 1 Heats of combustion as a function of fuel density ing synthesis, and this strain energy is released during combustion (Chapter 2). Research by Robert Moriarty at the University of Illinois at Chicago focussed on the synthesis of cubane analogues which contained polyunsaturated side-chains which in turn could be used as starting materials for the production of highenergy derivatives.

19 Synthesis of substituted cubanes. 1]hept-2-ene. The polymerization reactions shown in Fig. 20 were attempted. While literature procedures are known for the syntheses of 16, 17, and 18, neither of these three compounds was commercially available. Laboratory syntheses of 16, 17, and 18 reproduced the procedures and yields found in the chemical literature. 20 Ring-opening metathesis reactions Compound 22 is a surprisingly stable ROMP catalyst (in both protic and aprotic media). It was made available via the courtesy of Dr.

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